通过加入粘土纳米填料来提高高密度聚乙烯的介电性能
摘要
制备了钠蒙脱石纳米填料组成的高密度聚乙烯。通过扫描电子显微镜对其形貌进行了优化和表征,显示了聚合物纳米复合材
料的形成。测定了所制备样品的热稳定性和介电性能。热重分析结果表明,聚合物纳米复合材料的热稳定性高于基质聚合
物。研究表明,与碱性聚合物相比,聚合物纳米复合材料具有非常不同的介电特性。粘土-纳米填料的加入提高了介电击穿
强度。介电常数(εr)和耗散因子(Tanδ)研究在频率范围200Hz2MHz在室温下表明增强已经发生在εr和Tanδ高物材料的添加与纯
材料相比。
关键词
全文:
PDF参考
[1]Du,B.X.andLiu,H.J.(2010)EffectsofAtmospheric
PressureonTrackingFailureofGamma-RayIrradiatedPolymer
InsulatingMaterials.IEEETransactionsonDielectricsand
ElectricalInsulation,17,541-547.http://dx.doi.org/10.1109/
TDEI.2010.5448110
[2]Carmona,F.(1989)ConductingFilledPolymers.
PhysicaA,157,461-469.http://dx.doi.org/10.1016/0378-
4371(89)90344-0
[3]Bai,Y.,Cheng,Z.-Y.,Bharti,V.,Xu,H.S.andZhang,
Q.M.(2000)HighDielectric-ConstantCeramic-PowderPolymer
Composites.AppliedPhysicsLetters,76,3804-3806.http://
dx.doi.org/10.1063/1.126787
[4]Ueki,M.M.andZanin,M.(1999)InfluenceofAdditives
ontheDielectricStrengthofHigh-DensityPolyethylene.IEEE
TransactionsonDielectricsandElectricalInsulation,6,876-
881.http://dx.doi.org/10.1109/94.822030
[5]Messersmith,P.B.andGiannelis,E.P.(1994)Synthesis
andCharacterizationofLayeredSilicate-EpoxyNanocomposites.
ChemistryofMaterial,6,1719-1725.http://dx.doi.org/10.1021/
cm00046a026
[6]Ray,S.S.andOkamoto,M.(2003)Polymer/Layered
SilicateNanocomposites:AReviewfromPreparationto
Processing.ProgressinPolymerScience,28,1539-1641.http://
dx.doi.org/10.1016/j.progpolymsci.2003.08.002
[7]Gensler,R.,Groppel,P.,Muhrer,V.andMuller,N.
(2002)ApplicationsofNanoparticlesinPolymersforElectronic
andElectricalEngineering.ParticleandParticleSystems
Characterization,19,293-299.http://dx.doi.org/10.1002/1521-
4117(200211)19:53.0.CO;2-N
[8]Tanaka,T.(2005)DielectricNanocompositeswith
InsulatingProperties.IEEETransactionsonDielectricsand
ElectricalInsulation,12,914-928.http://dx.doi.org/10.1109/
TDEI.2005.1522186
[9]Cao,Y.,Irwin,P.C.andYounsi,K.(2004)TheFuture
ofNanodielectricsintheElectricalPowerIndustry.IEEE
TransactionsonDielectricsandElectricalInsulation,11,797-
807.http://dx.doi.org/10.1109/TDEI.2004.1349785
[10]Imai,T.,Sawa,F.,Ozaki,T.,Inoue,Y.,Shimizu,T.
andTanaka,T.(2006)ComparisonofInsulationBreakdown
PropertiesofEpoxyNanocompositesunderHomogeneousand
DivergentElectricFields.2006IEEEConferenceonElectrical
InsulationandDielectricPhenomena,Kansas,15-18October
2006,306-309.http://140.98.202.196/xpl/login.jsp?tp=&arnumb
er=4105431&url=http%3A%2F%2F140.98.202.196%2Fstamp%
2Fstamp.jsp%3Ftp%3D%26arnumber%3D4105431
[11]Lewis,T.J.(2004)InterfacesAretheDominantFeature
ofDielectricsattheNanometricLevel.IEEETransactionson
DielectricsandElectricalInsulation,11,739-753.http://dx.doi.
org/10.1109/TDEI.2004.1349779
[12]Roy,M.,Nelson,J.K.,MacCrone,R.K.andSchadler,
L.S.(2005)PolymerNanocompositeDielectrics—The
RoleoftheInterface.IEEETransactionsonDielectricsand
ElectricalInsulation,12,629-643.http://dx.doi.org/10.1109/
TDEI.2005.1511089
[13]Ajayan,P.M.,Schadler,L.S.andBraun,P.V.(2003)
NanocompositeScienceandTechnology.JohnWiley&Sons
Inc.,NewYork.http://dx.doi.org/10.1002/3527602127
[14]Liu,X.H.andWu,Q.J.(2001)PP/ClayNanocomposites
PreparedbyGrafting-MeltIntercalation.ElsevierPolymer,42,
10013-10019.http://dx.doi.org/10.1016/S0032-3861(01)00561-4
[15]Hassan,M.A.,El-Sayed,I.,Nour,M.A.andMohamed,
A.A.(2012)FlammabilityPropertiesofHDPENanocomposites
BasedonModificationofNa-MMTwithOrganoSilaneand
AmmoniumPhosphateMonoandDiBasic.ElixirApplied
Chemistry,46,8328-8333.http://www.elixirpublishers.com/
index.php?route=articles/category&path=305_306&page=9
[16]Li,L.(2011)DielectricPropertiesofAgedPolymers
andNanocomposites.Ph.D.Thesis,IowaStateUniversity,Iowa.
[17]Singha,S.andThomas,M.J.(2008)Permittivityand
TanDeltaCharacteristicsofEpoxyNanocomposites.IEEE
TransactionsonDielectricsandElectricalInsulation,15,2-11.
http://dx.doi.org/10.1109/T-DEI.2008.4446731
[18]Singha,S.andThomas,M.J.(2008)Dielectric
PropertiesofEpoxyNanocomposites.IEEETransactionson
DielectricsandElectricalInsulation,15,12-23.http://dx.doi.
org/10.1109/T-DEI.2008.4446732
DOI: http://dx.doi.org/10.12361/2661-3506-04-22-110881
Refbacks
- 当前没有refback。