超声波碱解预处理促进市政污泥厌氧消化的研究进展

张 博¹, 季 民¹, 赵 益华², 马 宁², 马 同宇²
1、天津大学环境科学与工程学院 天津
2、天津生态城水务投资建设有限公司 天津

摘要

随着水资源的需求和利用量逐渐增加,污水处理厂的数量也越来越多,污水处理的副产物剩余污泥的产量也不断增加。剩余污泥中含有大量的多种有机组分,如果不进行妥善处置,会对周边环境带来极大的污染隐患。厌氧消化技术是剩余污泥处理处置领域的研究热点之一,可以实现污泥的无害化、减量化、资源化、稳定化。然而,由于厌氧消化技术存在着水解速率慢、产气效率低等问题,大大的制约了厌氧消化技术的应用和发展。超声波和碱解技术对污泥预处理破解程度较高,可以显著改善污泥的厌氧消化特性。

关键词

超声波、碱解、预处理、剩余污泥、厌氧消化

参考

杨春雪.嗜热菌强化剩余污泥水解及短链脂肪酸积累规律研究[D].哈尔滨工业大学,2015. [2]ZhangJ,XueY,EshtiaghiN,etal.EvaluationofThermalHydrolysisEfficiencyofMechanically DewateredSewageSludgeViaRheologicalMeasurement[J].WaterResearch,2017,116:34-43. [3]ChenY,ChengJJ,CreamerKS.InhibitionofAnaerobicDigestionProcess:AReview[J].Biore- sourceTechnology,2008,99(10):4044-4064. [4]AhmedMJK,AhmaruzzamanM.AReviewOnPotentialUsageofIndustrialWasteMaterialsfor BindingHeavyMetalIonsFrom AqueousSolutions[J].JournalofWaterProcessEngineering,2016,10: 39-47.[5]StiborovaH,KolarM,VrkoslavovaJ,etal.LinkingToxicityProfilestoPollutantsinSludgeand Sediments[J].JournalofHazardousMaterials,2017,321:672-680. [6]王平.热水解厌氧消化工艺的分析和应用探讨[J].给水排水,2015(01):33-38. [7]丁瑾.电化学-生物法结合的污泥稳定化新型技术的研究[D].上海交通大学,2010. [8]YuanH,YuB,ChengP,etal.Pilot-ScaleStudyofEnhancedAnaerobicDigestionofWasteAc- tivatedSludgebyElectrochemicalandSodium HypochloriteCombinationPretreatment[J].International Biodeterioration& Biodegradation,2016,110:227-234. [9]JinY,LiH,MaharRB,etal.CombinedAlkalineandUltrasonicPretreatmentofSludgeBefore AerobicDigestion[J].JEnvironSci(China),2009,21(3):279-284. [10]KumarAwasthiM,WangM,PandeyA,etal.HeterogeneityofZeoliteCombinedwithBiochar PropertiesasaFunctionofSewageSludgeCompostingandProductionofNutrient-RichCompost[J]. WasteManagement,2017,68:760-773. [11]LiR,TengW,LiY,etal.PotentialRecoveryofPhosphorusDuringtheFluidizedBedIncinera- tionofSewageSludge[J].JournalofCleanerProduction,2017,140:964-970. [12]晏发春,汪恂,张雷.高温热水解预处理厌氧消化技术实例分析[J].中国给水排水,2016(18): 35-37.[13]王涛,王鑫洁.污泥厌氧消化技术现状及应注意的问题[J].中国环保产业,2013(05):49-54. [14]DuanN,DongB,WuB,etal.High-SolidAnaerobicDigestionofSewageSludgeUnderMeso- philicConditions:FeasibilityStudy[J].BioresourceTechnology,2012,104:150-156. [15]CanoR,Pérez-ElviraSI,Fdz-PolancoF.EnergyFeasibilityStudyofSludgePretreatments: AReview[J].AppliedEnergy,2015,149:176-185. [16]PilliS,YanS,TyagiRD,etal.AnaerobicDigestionofUltrasonicatedSludgeatDifferentSolids Concentrations- ComputationofMass-EnergyBalanceandGreenhouseGasEmissions[J].Journalof EnvironmentalManagement,2016,166:374-386. [17]CarrèreH,DumasC,BattimelliA,etal.PretreatmentMethodstoImproveSludgeAnaerobic Degradability:AReview[J].JournalofHazardousMaterials,2010,183(1-3):1-15. [18]FangW,ZhangP,ZhangG,etal.EffectofAlkalineAdditionOnAnaerobicSludgeDigestion withCombinedPretreatmentofAlkalineandHighPressureHomogenization[J].BioresourceTechnology, 2014,168:167-172. 60

IndustrialTechnology,工业技术(2)2019,1 ISSN:2661-3662(Print) [19]ChoS,JuH,LeeJ,etal.Alkaline-MechanicalPretreatmentProcessforEnhancedAnaerobic DigestionofThickenedWasteActivatedSludgewithaNovelCrushingDevice:PerformanceEvaluationand EconomicAnalysis[J].BioresourceTechnology,2014,165:183-190. [20]BragugliaC M,GianicoA,MininniG.ComparisonBetweenOzoneandUltrasoundDisintegration OnSludgeAnaerobicDigestion[J].JournalofEnvironmentalManagement,2012,95:S139-S143. [21]SahinkayaS.DisintegrationofMunicipalWasteActivatedSludgebySimultaneousCombinationof AcidandUltrasonicPretreatment[J].ProcessSafetyandEnvironmentalProtection,2015,93:201-205. [22]XuJ,YuanH,LinJ,etal.EvaluationofThermal,Thermal-Alkaline,AlkalineandElectro- chemicalPretreatmentsOnSludgetoEnhanceAnaerobicBiogasProduction[J].JournaloftheTaiwanIn- stituteofChemicalEngineers,2014,45(5):2531-2536. [23]ChoH U,ParkSK,HaJH,etal.AnInnovativeSewageSludgeReductionbyUsingaCom- bined MesophilicAnaerobicand Thermophilic AerobicProcesswith Thermal-AlkalineTreatmentand SludgeRecirculation[J].JournalofEnvironmentalManagement,2013,129:274-282. [24]ZhangY,ZhangP,ZhangG,etal.SewageSludgeDisintegrationbyCombinedTreatmentofAl- kaline+HighPressureHomogenization[J].BioresourceTechnology,2012,123:514-519. [25]KuglarzM,KarakashevD,AngelidakiI.MicrowaveandThermalPretreatmentasMethodsfor IncreasingtheBiogasPotentialofSecondarySludgeFrom Municipal WastewaterTreatmentPlants[J]. BioresourceTechnology,2013,134:290-297. [26]ZhenG,LuX,LiY,etal.CombinedElectrical-AlkaliPretreatmenttoIncreasetheAnaerobic HydrolysisRateofWasteActivatedSludgeDuringAnaerobicDigestion[J].AppliedEnergy,2014,128: 93-102. [27]TianX,WangC,TrzcinskiAP,etal.InterpretingtheSynergisticEffectinCombinedUltrasoni- cation– OzonationSewageSludgePre-Treatment[J].Chemosphere,2015,140:63-71. [28]TianX,WangC,TrzcinskiAP,etal.InsightsOntheSolubilizationProductsAfterCombined AlkalineandUltrasonicPre-TreatmentofSewageSludge[J].JournalofEnvironmentalSciences,2015, 29:97-105. [29]PilliS,BhuniaP,YanS,etal.UltrasonicPretreatmentofSludge:A Review[J].Ultrasonics Sonochemistry,2011,18(1):1-18. [30]杨洁.碱和超声波预处理技术促进污泥厌氧消化效能及机理研究[D].天津大学,2008. [31]WangF,WangY,JiM.MechanismsandKineticsModelsforUltrasonicWasteActivatedSludge Disintegration[J].JournalofHazardousMaterials,2005,123(1-3):145-150. [32]AsgharzadehahmadiS,AbdulRamanA A,ParthasarathyR,etal.SonochemicalReactors:Re- view OnFeatures,AdvantagesandLimitations[J].RenewableandSustainableEnergyReviews,2016,63: 302-314. [33]GonzeE,PillotS,ValetteE,etal.UltrasonicTreatmentofanAerobicActivatedSludgeina BatchReactor[J].ChemicalEngineeringandProcessing:ProcessIntensification,2003,42(12):965-975. [34]DewilR,BaeyensJ,GoutvrindR.TheUseofUltrasonicsintheTreatmentofWasteActivated Sludge[J].ChineseJournalofChemicalEngineering,2006,14(1):105-113. [35]A.Tiehm K N U N.TheUseofUltrasoundtoAcceleratetheAnaerobicDigestionofSewage Sludge[J].WaterScience& Technology,1997,11(36):121-128. [36]ShimizuT,KudoK,NasuY.Anaerobic Waste-ActivatedSludgeDigestion-A Bioconversion MechanismandKineticModel[J].BiotechnologyandBioengineering,1993,11(41):1082-1091. [37]WangF,LuS,JiM.ComponentsofReleasedLiquidFrom Ultrasonic WasteActivatedSludge61

IndustrialTechnology,工业技术(2)2019,1 ISSN:2661-3662(Print) Disintegration[J].UltrasonicsSonochemistry,2006,13(4):334-338. [38]WangQ,KuninobuM,KakimotoK,etal.UpgradingofAnaerobicDigestionofWasteActivated SludgebyUltrasonicPretreatment[J].1999,68(3):309-313. [39]ChuCP,LeeDJ,ChangBV,etal."Weak"UltrasonicPre-TreatmentOnAnaerobicDigestion ofFlocculatedActivatedBiosolids[J].WaterRes,2002,36(11):2681-2688. [40]BougrierC,CarrèreH,DelgenèsJP.SolubilisationofWaste-ActivatedSludgebyUltrasonic Treatment[J].ChemicalEngineeringJournal,2005,106(2):163-169. [41]Tiehm A,NickelK,ZellhornM,etal.UltrasonicWasteActivatedSludgeDisintegrationforIm- provingAnaerobicStabilization[J].WATERRESEARCH,2001,35(8):2003-2009. [42]TyagiV K,LoS,AppelsL,etal.UltrasonicTreatmentofWasteSludge:AReviewonMecha- nismsandApplications[J].CriticalReviewsinEnvironmentalScienceand Technology,2014,44(11): 1220-1288. [43]XieR,XingY,GhaniY A,etal.Full-ScaleDemonstrationofan UltrasonicDisintegration TechnologyinEnhancingAnaerobicDigestionofMixedPrimaryandThickenedSecondarySewageSludge [J].JournalofEnvironmentalEngineeringandScience,2007,6(5):533-541. [44]HoganF,MormedeS,ClarkP,etal.UltrasonicSludgeTreatmentforEnhancedAnaerobicDi- gestion[J].WaterScience& Technology,2004,9(50):25-32. [45]GogatePR,MujumdarS,PanditAB.Large-ScaleSonochemicalReactorsforProcessIntensifi- cation:DesignandExperimentalValidation[J].JournalofChemicalTechnology & Biotechnology,2003, 78(6):685-693. [46]NickelK,NeisU.UltrasonicDisintegrationofBiosolidsforImprovedBiodegradation[J].Ultra- sonicsSonochemistry,2007,14(4):450-455. [47]SalsabilM R,ProrotA,CasellasM,etal.Pre-TreatmentofActivatedSludge:EffectofSonica- tionOn Aerobicand AnaerobicDigestibility[J].ChemicalEngineeringJournal,2009,148(2-3):327 -335.[48]DharBR,NakhlaG,RayM B.Techno-EconomicEvaluationofUltrasoundandThermalPre- treatmentsforEnhanced AnaerobicDigestionof Municipal WasteActivatedSludge[J].Waste Manage- ment,2012,32(3):542-549. [49]CsokaL,KatekhayeSN,GogatePR.ComparisonofCavitationalActivityinDifferentConfigura- tionsofSonochemicalReactorsUsingModelReactionSupportedwithTheoreticalSimulations[J].Chemical EngineeringJournal,2011,178:384-390. [50]Bhirud U.UltrasonicBath with LongitudinalVibrations:A NovelConfigurationforEfficient WastewaterTreatment[J].UltrasonicsSonochemistry,2004,11(3-4):143-147. [51]GogatePR,KatekhayeSN.AComparisonoftheDegreeofIntensificationDuetotheUseofAd- ditivesinUltrasonicHornandUltrasonicBath[J].ChemicalEngineeringandProcessing:ProcessIntensifi- cation,2012,61:23-29. [52]XuZ,YasudaK,KodaS.NumericalSimulationofLiquidVelocityDistributioninaSonochemical Reactor[J].UltrasonicsSonochemistry,2013,20(1):452-459. [53]GogatePR,SivakumarM,PanditAB.DestructionofRhodamineB UsingNovelSonochemical ReactorwithCapacityof7.5L[J].SeparationandPurificationTechnology,2004,34(1-3):13-24. [54]GogatePR,MujumdarS,PanditAB.SonochemicalReactorsforWasteWaterTreatment:Com- parisonUsingFormicAcidDegradationasa ModelReaction[J].AdvancesinEnvironmentalResearch, 2003,7(2):283-299. 62

IndustrialTechnology,工业技术(2)2019,1 ISSN:2661-3662(Print) [55]GogatePR,SutkarV S,PanditA B.SonochemicalReactors:ImportantDesignandScaleUp ConsiderationswithaSpecialEmphasisOn HeterogeneousSystems[J].ChemicalEngineeringJournal, 2011,166(3):1066-1082. [56]CassiniST,AndradeM CE,AbreuTA,etal.AlkalineandAcidHydrolyticProcessesinAero- bicandAnaerobicSludges:EffectOnTotalEPSandFractions[J].WaterScienceandTechnology,2006, 53(8):51-58. [57]LiH,LiC,LiuW,etal.OptimizedAlkalinePretreatmentofSludgeBeforeAnaerobicDigestion [J].BioresourceTechnology,2012,123:189-194. [58]KimJ,ParkC,KimT H,etal.EffectsofVariousPretreatmentsforEnhancedAnaerobicDiges- tionwith Waste ActivatedSludge[J].JournalofBioscience &Bioengineering,2003,95(3):217 -275.[59]LinJ,ChangC,ChangS.EnhancementofAnaerobicDigestionofWasteActivatedSludgebyAl- kalineSolubilization[J].BioresourceTechnology,1997,62:85-90. [60]RajanRV,LinJ,RayBT.Low-LevelChemicalPretreatmentforEnhancedSludgeSolubiliza- tion[J].WaterPollutionControlFederation,1989,11(61):1678-1683. [61]UmaRaniR,AdishKumarS,KaliappanS,etal.EnhancingtheAnaerobicDigestionPotentialof DairyWasteActivatedSludgebyTwoStepSono-AlkalizationPretreatment[J].UltrasonicsSonochemis- try,2014,21(3):1065-1074. [62]ZhangL,JahngD.EnhancedAnaerobicDigestionofPiggeryWastewaterbyAmmoniaStripping: EffectsofAlkaliTypes[J].JournalofHazardousMaterials,2010,182(1-3):536-543. [63]Al-FaifiH,Al-OmranA M,Nadeem M,etal.SoilDeteriorationasInfluencedbyLandDis- posalofRejectBrineFrom Salbukh WaterDesalinationPlantatRiyadh,SaudiArabia[J].Desalination, 2010,250(2):479-484. [64]KhorW C,RabaeyK,VervaerenH.LowTemperatureCalcium HydroxideTreatmentEnhances AnaerobicMethane Production From (Extruded)Biomass[J].Bioresource Technology,2015,176: 181-188. [65]ParkND,HelleSS,ThringR W.CombinedAlkalineandUltrasoundPre-TreatmentofThick- enedPulp Mill WasteActivatedSludgeforImproved AnaerobicDigestion[J].BiomassandBioenergy, 2012,46:750-756. [66]ZawiejaI,WolnyL,WolskiP.InfluenceofExcessiveSludgeConditioningOntheEfficiencyof AnaerobicStabilizationProcessandBiogasGeneration[J].Desalination,2008,222(1-3):374-381. [67]Kim D,JeongE,OhS,etal.Combined(Alkaline+Ultrasonic)PretreatmentEffectOnSewage SludgeDisintegration[J].WaterResearch,2010,44(10):3093-3100.