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基于聚乙烯的含 Co 和 Ni 纳米颗粒的混合磁性材料

Alexander Yu. Vasil’kov, Alexander V. Budnikov, Alexander V. Naumkin
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov st. 119991 Moscow, Russia

摘要


通过金属蒸气合成法制备了基于 HDPE 填充 Со 和 Ni 纳米颗粒的新型混合磁性材料。金属 - 聚合物复合材料的特性已经被阐明为 MVS 参数和金属性质的函数。法拉第方法已被用于表征这些系统的磁性能。已经采用一些X射线和同步辐射技术研究了样品的微观结构,包括 XRD、EXAFS 和 SAXS。核心级和价带光谱是利用XPS 测量的。在 C 1s 光谱中记录了结合能为 282.8 eV 的 C-Ni 键的峰值。结果表明,具有相似成分的纳米复合材料的特性由合成条件和合成后的因素决定。

关键词


混合材料;磁性能;高密度聚乙烯;钴;镍;纳米颗粒;金属蒸气合成;XPS



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