基于聚乙烯的含 Co 和 Ni 纳米颗粒的混合磁性材料

Alexander Yu. Vasil’kov, Alexander V. Budnikov, Alexander V. Naumkin
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov st., Moscow 119991, Russia.

摘要

通过金属蒸气合成法制备了基于 HDPE 填充 Со 和 Ni 纳米颗粒的新型混合磁性材料。金属 - 聚合物复合材料的特性已经被阐明为 MVS 参数和金属性质的函数。法拉第方法已被用于表征这些系统的磁性能。已经采用一些X 射线和同步辐射技术研究了样品的微观结构，包括 XRD、EXAFS 和 SAXS。核心级和价带光谱是利用 XPS 测量的。在 C 1s 光谱中记录了结合能为 282.8 eV 的 C-Ni 键的峰值。结果表明，具有相似成分的纳米复合材料的特性由合成条件和合成后的因素决定。

关键词

混合材料；磁性能；高密度聚乙烯；钴；镍；纳米颗粒；金属蒸气合成；XPS

参考

[1] Vasil’kov, A.Y., Migulin, D.A., Naumkin, A.V., Belyakova, O.A., et al. (2016) Preparation of Novel Hybrid Materials Based on Core-shell Polyorganosilsesquioxanes

M o d i f i e d w i t h I r o n N a n o p a r t i c l e s . M e n d e l e e v Communications, 26, 187–190.

[2] Rubina, M.S., Kamitov, E.E., Zubavichus, Y.V., Peters, G.S., et al. (2016) Collagen-chitosan Scaffold Modified with Au and Ag Nanoparticles: Synthesis and Structure. Applied Surface Science, 366, 365–371.

[3] Tsodikov, M.V., Ellert, O.G., Nikolaev, S.A., Arapova, O.V., et al. (2017) The Role of Nanosized Nickel Particles in Microwave-assisted Dry Reforming of Lignin. Chemical Engineering Journal, 309, 628–637.

[4] Rubina, M.S., Vasil’kov, A.Y., Naumkin, A.V., Shtykova, E.V., et al. (2017) Synthesis and Characterization of Chitosan–copper Nanocomposites and Their Fungicidal Activity Against Two Sclerotia-forming Plant Pathogenic Fungi. Journal of Nanostructure in Chemistry, 7, 249–258.

[5] Selwood, P.W. (1975) Chemisorption and Magnetization. Academic Press, New York, 164.

[6] Chernyshov, A.A., Veligzhanin, A.A., Zubavichus, Y.V. (2009) Structural Materials Science End-station at the Kurchatov Synchrotron Radiation Source: Recent Instrumentation Upgrades and Experimental Results. Nuclear Instruments & Methods in Physics Research, 603, 95–98.

[7] Davis, S.C., Severson, S.J., Klabunde, K.J. (1981) Clustering of Metal Atoms in Organic Media. 8. Low temperature Cleavage of Alkanes by Small Nickel Particles Resulting in Stable Nickel-organic Composites with Unusual Magnetic and Chemical Properties. Journal of American

Chemical Society, 103, 3024–3029.

[8] Naumkin, A.V., Vasil’kov, A.Y., Volkov, I.O., Smirnov, V.V., et al. (2007) X-ray Photoelectron Spectra and Structure of Composites Prepared via Deposition of Au, Ni, and Au + Ni Nanoparticles on SiO2 from Colloidal Solutions in Triethylamine. Inorganic Materials, 43, 381–385.

[9] Vasil’kov, A.Y., Nikolaev, S.A., Smirnov, V.V., Naumkin, A.V., et al. (2007) An XPS Study of the Synergetic Effect of Gold and Nickel Supported on SiO2 in the Catalytic Isomerization of Allylbenzene. Mendeleev Communications, 17, 268–270.

[10] Lian, K., Thorpe, S.J., Kirk, D.W. (1992) Electrochemical and Surface Characterization of

Electrocatalytically Active Amorphous Ni-Co Alloys. Electrochimica Acta, 37, 2029–2041.

[11] Venezia, A.M., Bertoncello, R., Deganello, G. (1995) X-ray Photoelectron Spectroscopy Investigation of Pumice supported Nickel Catalysts. Surface & Interface Analysis, 23, 239–247.

[12] Workie, B., Kounaves, S.P., Aksu, M.L., Davies, G., et al. (1995) Electrodeposition of Metal Alloy and Mixed Oxide Films Using a Single-precursor Tetranuclear Coppernickel Complex. Journal of the Electrochemical Society, 142, 3357–3365.

[13] Bianchi, C.L., Cattania, M.G., Villa, P. (1993) XPS Characterization of Ni and Mo Oxides Before and After “in situ” Treatments. Applied Surface Science, 70–71, 211–216.

[14] McIntyre, N.S., Chan, T.C., Chen, C. (1990) Characterization of Oxide Structures Formed on Nickel chromium Alloy during Low Pressure Oxidation at 500–600 ℃ . Oxidation of Metals, 33, 457–479.

[15] Mansour, A.N. (1994) Characterization of NiO by XPS. Surface Science Spectra, 3, 239–246.

[16] Lian, K.K., Kirk, D.W., Thorpe, S.J. (1995) Investigation of a “Two-State” Tafel Phenomenon for the Oxygen Evolution Reaction on an Amorphous NiCo Alloy. Journal of the Electrochemical Society, 142, 3704–3712.

[17] M a n s o u r , A . N . , M e l e n d r e s , C . A . ( 1 9 9 4 ) Characterization of α-Ni(OH)2 by XPS. Surface Science Spectra, 3, 255–262.

[18] M a n s o u r , A . N . , M e l e n d r e s , C . A . ( 1 9 9 4 ) Characterization of Ni2O36H2O by XPS. Surface Science Spectra, 3, 263–270.

[19] M a n s o u r , A . N . , M e l e n d r e s , C . A . ( 1 9 9 4 ) Characterization of Electrochemically Prepared γ-NiOOH by XPS. Surface Science Spectra, 3, 271–278.

[20] M a n s o u r , A . N . , M e l e n d r e s , C . A . ( 1 9 9 4 ) Characterization of Slightly Hydrated Ni(OH)2 by XPS. Surface Science Spectra, 3, 247–254.

[21] Mansour, A.N. (1994) Characterization of β-Ni(OH)2 by XPS. Surface Science Spectra, 3, 239–246.

[22] Chen, X.A., Chen, X.H., Zhang, F.Q., Yang, Z., et al. (2013) One-pot Hydrothermal Synthesis of Reduced Graphene Oxide/Carbon Nanotube/α-Ni(OH)2 Composites for High Performance Electrochemical Supercapacitor. Journal of Power Sources, 243, 555–561.

[23] Naumkin, A.V., Kraut-Vass, A., Gaarenstroom, S.W. and Powell, C.J. (2012) NIST X-ray Photoelectron Spectroscopy Database. Version 4.1. Gaithersburg: National Institute of Standards and Technology. https://srdata.nist.gov/xps/

[24] Payne, B.P., Biesinger, M.C., McIntyre, N.S. (2012) Use of Oxygen/Nickel Ratios in the XPS Characterization of Oxide Phases on Nickel Metal and Nickel Alloy Surfaces. Journal of Electron Spectroscopy and Related Phenomena, 185, 159–166.

[25] Payne, B.P., Biesinger, M.C., McIntyre, N.S. (2009) The Study of Polycrystalline Nickel Metal Oxidation by Water Vapour. Journal of Electron Spectroscopy & Related Phenomena, 175, 55–65.

[26] Biesinger, M.C., Lau, L.W.M., Gerson, A.R. and Smart, R.S.C. (2012) The Role of the Auger Parameter in XPS Studies of Nickel Metal, Halides and Oxides. Physical Chemistry Chemical Physics, 14, 2434–2442.

[27] Tanuma, S., Powell, C.J., Penn, D.R. (2011) Calculations of Electron Inelastic Mean Free Paths. IX. Data for 41 Elemental Solids over the 50 eV to 30 keV Range. Surface and Interface Analysis, 43, 689–713.

[28] Powell, C.J., Jablonski, A. (2017) NIST Electron Inelastic-mean-free-path Database 71. Version 1.1. Gaithersburg: National Institute of Standards and Technology.

https://www.nist.gov/publications/nist-electron-inelasticmean-free

-path-database-71-version-11

[29] Henderson, M.A. (2002) The Interaction of Water with Solid Surfaces: Fundamental Aspects Revisited. Surface Science Reports, 46, 1–308.

[30] Moulder, J.F., Stickle, W.F., Sobol, P.E. and Bomben, K.D. (1992) Handbook of X-ray Photoelectron Spectroscopy: A Reference Book of Standard Spectra for Identification and Interpretation of XPS Data. In: Chastain, J., Ed., Physical Electronics Division, Perkin-Elmer Corporation, Eden Prairie, Minnesota, 261.