长余辉玻璃陶瓷制备方法与体系的研究进展

宋 拓, 潘 雪怡, 赵 亚娟, 夏 威
温州大学化学与材料工程学院 浙江温州 325400

摘要

长余辉玻璃陶瓷是一种新型的节能环保发光材料，在安全警示、道路信号、光催化、信息存储以及生物医疗等领域得到广泛应用。本文系统综述了长余辉玻璃陶瓷的制备方法和材料体系，并分析了高温熔融法、二步法和溶胶-凝胶法的优缺点。同时，研究了铝酸盐体系和硅酸盐体系长余辉玻璃陶瓷的特性，并探讨了亟需解决的问题。

关键词

长余辉；玻璃陶瓷；制备方法；发光材料

参考

[1]L. Fernández-Rodríguez, D. Levy, M. Zayat, et al. (2021) Processing and luminescence of Eu/Dy-doped Sr2MgSi2O7 glass-ceramics. Journal of the European Ceramic Society, 41, 811-822.[2]Leonnam Gotardo Mer í zio, Thiago Augusto Lodi, Everton Bonturim, et al. (2022) Persistent luminescent phosphor-in-glass composites based on NaPO3-Ga2O3 glasses loaded with Sr2MgSi2O7:Eu2+, Dy3+. Optical Materials, 134, 113046.[3]Salhah D. Al-Qahtani, Seraj Omar Alzahrani, Razan M. Snari, et al. (2022) Preparation of photoluminescent and photochromic smart glass window using sol-gel technique and lanthanides-activated aluminate phosphor. Ceramics International, 48, 17489-17498.[4]Huidan Zeng, Zhenyu Lin, Qiang Zhang, et al. (2011) Green emission from Eu2+/Dy3+ codoped SrO-Al2O3-B2O3 glass-ceramic by ultraviolet light and femtosecond laser irradiation. Materials Research Bulletin, 46, 319-322.[5]V. Lahti, N. Ojha, S. Vuori, et al. (2021) Preparation of glass-based composites with green upconversion and persistent luminescence using modified direct doping method. Materials Chemistry and Physics, 274, 125164.[6]王洪杰，马腾飞，张粟等. 激活 CaO-MgO-SiO2 长余辉玻璃发光性质[J]. 应用化学，2016, 33(1):63-69.